• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    STEEL PLATE FOR PRESSING AND PRODUCTION METHOD OF A HOT-PRESSED COMPONENT USING THE SAME. The present invention relates to a hot pressed steel plate that is capable of suppressing scaling or ZnO in hot pressing and excellent in oxidation resistance, and a method for producing a hot pressed component using the plate give steel. The hot pressing steel plate includes a base steel plate and a coating layer that is formed on the surface of the base steel plate at a coating weight of 10 to 90 g / m2 and contains 10 to 25% by weight of Ni and the balance being Zn and the inevitable impurities.
    公开号:BR112013012551B1
    申请号:R112013012551-9
    申请日:2011-11-18
    公开日:2021-01-12
    发明作者:Seiji Nakajima；Tatsuya Miyoshi；Hiroki Nakamaru
    申请人:Jfe Steel Corporation；
    IPC主号:
    专利说明:

    [0001] [1] The present invention relates to a hot pressed steel plate suitable for the production of components, such as suspension components or structural components of an automobile chassis, by hot pressing and a method for producing a hot-pressed component using the hot-pressed steel plate. Background
    [0002] [2] Conventionally, many components such as suspension components or structural components of an automobile chassis are produced by pressing a sheet of steel that has a predetermined strength. In recent years, from the point of view of conserving the global environment, the weight reduction of car chassis is desired, and efforts are being made to reduce the thickness of steel plates by increasing the strength of the steel plate. However, as the pressing capacity of the steel sheet deteriorates with the increase in strength of the steel sheet, in many cases it is difficult to shape the steel sheet into the desired shape.
    [0003] [3] Patent Literature 1 describes a pressing technique called hot pressing. This technique performs both easy and high-strength pressing by rapidly cooling a heated steel sheet at the same time as the heated steel sheet is pressed using a die-formed die and a punch. However, in this hot pressing, as the steel sheet is heated to a high temperature of about 950 ° C before hot pressing, scalings (iron oxide) are formed on the surface of the steel sheet. The scales formed on the surface of the steel plate are peeled during pressing and then the mold is damaged or the component surface is damaged after hot pressing. In addition, the scales that remain on the component surface cause a defect in appearance and a defect in paint adhesion. Consequently, the scale formed on the surface of the component is usually removed by blasting or shot blasting. These additional processes make the production process complicated, thus causing deterioration in productivity. In addition, components such as suspension components and car chassis structural components also require excellent anti-corrosion characteristics. However, an anti-corrosion coating such as a coating layer is not applied to the hot-pressed components produced by the processes mentioned above and therefore the anti-corrosion characteristics of the components are extremely insufficient.
    [0004] [4] In such a scenario, a hot pressing technique capable of suppressing scaling during heating prior to hot pressing and improving anti-corrosion characteristics is required. Therefore, a steel plate is proposed to which the anticorrosive coating such as the coating layer is applied, and a method for hot pressing a component using the steel plate. For example, Patent Literature 2 describes a production method for a hot-pressed component having excellent anti-corrosion characteristics. This production method includes a step of hot pressing a sheet coated with Zn or a Zn-based alloy, and a step of providing a compound based on Zn-Fe or a compound based on Zn-Fe-Al on the surface of the heated steel sheet. List of Citations Patent Literature
    [0005] [5] Patent Literature 1: UK Patent No. 1490535
    [0006] [6] Patent Literature 2: Japanese Patent No. 3663145 summary Technical problem
    [0007] [7] However, in the hot-pressed component produced by the method described in Patent Literature 2, there is a case where the defect in appearance and the defect in ink adhesion due to scaling are caused, and degradation of the characteristics is caused anticorrosion due to the generation of ZnO.
    [0008] [8] For the above reasons, an objective of the present invention is to provide a hot-pressed steel plate and a method for producing a hot-pressed component using the hot-pressed steel plate, in which the steel is excellent in oxidation resistance and capable of suppressing scaling in hot pressing. Solution to the Problem
    [0009] [9] The inventors acquired the knowledge described below as a result of intensive examination of a hot pressed steel plate.
    [0010] [10] Carepas are likely to be formed in a local portion, such as a defective portion of a coating layer, or fractures produced by hot pressing from a portion (starting point of fractures) in which metallic compounds Zn- Fe are formed during heating.
    [0011] [11] Carepas or ZnO are likely to be formed in the zinc coating layer having a melting point below 700 ° C.
    [0012] [12] To suppress scaling or ZnO, it is effective that the coating layer contains 10 to 25% by mass of Ni having a high melting point and the balance being Zn and the inevitable impurities,
    [0013] [13] According to the present invention, a steel plate for hot pressing is provided including: a base steel plate; and a coating layer that is formed on a surface of the base steel sheet at a coating weight of 10 to 90 g / m2 and contains 10 to 25% by mass of Ni and the balance Zn with the inevitable impurities.
    [0014] [14] It is preferable that the hot press steel sheet also includes at least one composite layer selected from the group consisting of Si-containing composite layer, Ti-containing composite layer, Al-containing composite layer, and Zr-containing composite layer, where the layer compound is formed in the coating layer.
    [0015] [15] The base steel plate, which is the steel plate before the coating layer is supplied and is the base for the coating layer, can have a composition of components having 0.15 to 0.5% by weight of C, 0.05 to 2.0 wt% of Si, 0.5 to 3.0 wt% of Mn, 0.1 wt% or less of P, 0.05 wt% or less of S, 0.1% by weight or less of Al, 0.01% by weight or less of N, and the balance being Fe and the inevitable impurities. It is preferable that the base steel sheet also contains at least one component selected from the group consisting of 0.01 to 1 wt% Cr, 0.2 wt% or less Ti, and 0.0005 to 0.08% by weight of B. It is preferable that the base steel plate also contains, in addition to / separately from at least one component mentioned above, 0.003 to 0.03% by weight of Sb.
    [0016] [16] According to the present invention, a method is provided for producing a hot-pressed component, the method including: heating the hot-pressed steel plate mentioned above to a temperature ranging from the transformation point Ac3 to 1000 ° C; and hot press the heated plate. Advantageous Effects of the Present Invention
    [0017] [17] According to the present invention, it is possible to produce steel sheet for hot pressing which is capable of suppressing scale formation or ZnO in hot pressing and excellent in resistance to oxidation. A hot-pressed component produced by the method of producing a hot-pressed component of the present invention using the hot-pressed steel plate of the present invention is excellent in appearance, and has excellent paint adhesion and anti-corrosion characteristics. Then, the hot-pressed component is suitable for the suspension component or structural component of an automobile chassis. Settings Description
    [0018] [18] Steel Plate for Hot Pressing
    [0019] [19] Coating layer
    [0020] [20] In the present invention, to suppress scaling or ZnO in hot pressing, a coating layer containing 10 to 25 wt% Ni and the balance of Zn and the inevitable impurities is provided on the surface of the steel sheet . The Ni content contained in the coating layer is adjusted to 10 to 25% by mass, with which a γ phase is formed having any crystalline structure between NÍ2Zn11, NiZn3, or Ni5Zn21 and having a high melting point of 881 ° C. Consequently, on heating, the formation of scalps or ZnO can be minimized. In addition, during heating, a metallic compound based on Zn-Fe is not formed, and then the scaling that accompanies the production of fractures is suppressed. In addition, a coating layer having such a composition remains on the steel plate as the γ phase even after the end of the hot pressing, thus exhibiting excellent anti-corrosion characteristics due to the anodic protection effect of Zn. Here, in the case where the Ni content is 10 to 25% by mass, the γ phase formation does not correspond to the data in the equilibrium diagram for the Ni-Zn alloy. This result can be brought about by the fact that the coating layer formation reaction, which is carried out by an electrogalvanizing or similar method, takes place in an unbalanced state. The γ phases of NÍ2Zn11, NiZn3, or Ni5Zn21 can be confirmed by an electronic diffraction method using an X-ray or TEM (Electronic Transmission Microscope) diffraction method. In addition, although the γ phase is, as described above, formed by adjusting the Ni content contained in the coating layer to 10 to 25% by mass, there is a case where a certain amount of η phase is also formed, depending on electroplating conditions and the like. In this case, to minimize the formation of scale and ZnO during heating, it is preferable to adjust the η phase content to 5% by weight or less. The content of the η phase is defined as the ratio of the phase weight to the total weight of the coating layer. For example, the content of phase η can be determined by the anodic or similar dissolution method.
    [0021] [21] The coating weight of the coating layer is adjusted to 10 to 90 g / m2 for each side. When the coating weight of the coating layer is less than 10 g / m2, the effect of Zn anodic protection is not sufficiently present. When the coating weight of the coating layer is greater than 90 g / m2, the effect of the protection anode of Zn becomes saturated thus increasing the cost of production.
    [0022] [22] Although the method for forming the coating layer is not particularly limited, it is preferable to use a well-known electrogalvanizing method.
    [0023] [23] At least one compote layer selected from a group consisting of a composite layer containing Si, a composite layer containing Ti, a composite layer containing Al and a composite layer containing Zr is also provided in the coating layer thus obtaining excellent adhesion of ink. To achieve this effect, it is preferable to adjust the thickness of the composite layer to 0.1 μm or more. In addition, it is preferable to adjust the thickness of the composite layer to 3.0 μm or less. When the thickness of the composite layer exceeds 3.0 μm, the composite layer becomes brittle thus causing a defect in paint adhesion. The thickness of the composite layer is most preferably within the range of 0.4 to 2.0 μm.
    [0024] [24] As a Si-containing compound, for example, silicone resin, lithium silicate, soda silicate, colloidal silica, and a silane binding agent are applicable. As a Ti-containing compound, for example, titanium such as lithium titanate or calcium titanate and a titanium bonding agent containing titanium alkoxide or a titanium compound of the chelating type are applicable as the base compound. As an Al-containing compound, for example, aluminates such as sodium aluminate or calcium aluminate, and an aluminum binding agent containing aluminum alkoxide or an aluminum compound of the chelating type are applicable as the base compound. As a compound containing Zr, for example, zirconates such as lithium zirconate and calcium zirconate and a zirconium bonding agent containing zirconium alkoxide or a chelating zirconium compound are applicable as the base compound. To form the aforementioned composite layer in the coating layer, at least one compound selected from the group consisting of Si-containing compound, Ti-containing compound, Al-containing compound and Zr-containing compound can be adhered to the coating layer and subsequently baked without being washed with water. As an adhesion treatment for these compounds, any application method, an immersion method, and a spray method can be used. After carrying out the application treatment by the compression coater, an immersion treatment or a spray treatment, it is also possible to adjust the amount of compound and uniform the appearance and thickness of the compound layer using the “air knife” method or a compression cylinder method. In addition, the maximum arrival temperature of the steel plate when cooking can be within the range of 40 to 200 ° C, and preferably within the range of 60 to 160 ° C.
    [0025] [25] Furthermore, the process for forming the composite layer mentioned above in the coating layer is not limited to the method mentioned above. It is also possible to form the composite layer mentioned above in the coating layer by a method described below; for example, a reactive treatment is performed so that the steel sheet having the coating layer is immersed in an acidic aqueous solution containing at least one cation selected from the group consisting of Si, Ti. Al and Zr and at least one selected anion of the group consisting of phosphoric acid ion, fluorine acid ion, and hydrofluoric acid ion, and then the steel plate is cooked by being washed with water or without being washed with water.
    [0026] [26] The composite layer mentioned above may contain solid inorganic lubricant. By the addition of solid inorganic lubricant, the dynamic friction coefficient at the time of hot pressing is reduced, thus improving the pressing work capacity.
    [0027] [27] As a solid inorganic lubricant, at least one substance selected from the group consisting of metallic sulfide (molybdenum disulphide, tungsten disulphide, or similar), a selenium compound (molybdenum selenide, tungsten selenide, or similar), graphite , fluoride, (graphite fluoride, calcium fluoride or similar), nitride (boron nitride, silicon nitride, or the like), borax, mica, metallic tin, and alkaline metal sulfate (sodium sulfate, potassium sulfate , or similar) is applicable. It is preferable that the content of the inorganic solid lubricant mentioned above contained in the composite layer is 0.1 to 20% by weight. In the event that the content of solid inorganic lubricant is 0.1% by weight or more, the composite layer is capable of providing a lubricating effect. In the case where the content of solid inorganic lubricant is 20% by mass or less, the adhesion of the paint is not degraded. Base Steel Sheet
    [0028] [28] To obtain the hot-pressed component having a tensile strength (TS) of 980 MPa or more, such as the base steel plate before coating, for example, a hot-rolled steel plate or a steel plate can be used. cold rolled steel including component composition having 0.15 to 0.5% by weight of C, 0.05 to 2.0% by weight of Si, 0.5 to 3% by weight of Mn, 0.1 % by weight or less than P, 0.05% by weight or less than S, 0.1% by weight or less than Al, 0.01% by weight or less than N, and the balance being Fe with the inevitable impurities . The reason why the content of each component element is limited is explained below. Here, "%" that expresses the component content means "% by mass" unless otherwise specified.
    [0029] [29] C: 0.15 to 0.5%
    [0030] [30] Component element C is an element that improves the strength of steel. To increase the tensile strength of the hot-pressed component to 980 MPa or more, it is necessary to adjust the C content to 0.15% or more. On the other hand, in the event that the C content exceeds 0.5%, the working capacity of the steel sheet as raw material is noticeably deteriorated. Therefore, the C content is within the range of 0.15 to 0.5%.
    [0031] [31] Si: 0.05 to 2.0%
    [0032] [32] The component element Si is an element that improves the strength of steel in the same way as in the case of C. To increase the tensile strength of the hot-pressed member to 980 MPa or more, it is necessary to adjust the Si content to 0.05% or more. On the other hand, in the case where the Si content exceeds 2.0%, the generation of the surface defect called red scale is greatly increased and, at the same time, the rolling load is increased or the ductility of the rolled steel sheet the hot is deteriorated. In addition, when carrying out the coating treatment so that the coating film containing Zn or Al as the main component is formed on the surface of the steel sheet, there is a case in which the Si content that exceeds 2.0 adversely affects the capacity coating processing. Therefore, the Si content is within the range of 0.05 to 2.0%.
    [0033] [33] Mn: 0.5 to 3%
    [0034] [34] The component element Mn is an effective element to improve the hardening capacity by suppressing the transformation of ferrite, and also effective to decrease the heating temperature before hot pressing by decreasing the transformation point Ac3. To show such effects, it is necessary to adjust the Mn content to 0.5% or more. On the other hand, in the event that the Mn content exceeds 3%, the Mn is segregated, and the uniformity of characteristics of the steel sheet as raw material and the hot-pressed component is reduced. Therefore, the Mn content is within the range of 0.5 to 3%.
    [0035] [35] P: 0.1% or less
    [0036] [36] When the P content exceeds 0.1%, P is segregated, and the uniformity of the characteristics of the steel sheet as the raw material of the hot-pressed component is decreased and, at the same time, its toughness is also decreased . Therefore, the P content is adjusted to 0.1% or less.
    [0037] [37] S: 0.05% or less
    [0038] [38] When the S content exceeds 0.05, the toughness of the hot-pressed component is decreased. Therefore, the S content is adjusted to 0.05% or less.
    [0039] [39] Al: 0.1% or less
    [0040] [40] When the Al content exceeds 0.1%, the working capacity or the hardening capacity of the steel sheet as a raw material is deteriorated. Therefore, the l content is adjusted to 0.1% or less.
    [0041] [41] N: 0.01% or less
    [0042] [42] When the N content exceeds 0.01%, nitride such as AlN is formed during hot rolling or heating prior to hot pressing, and the workability or hardening capacity of the steel sheet as raw material is deteriorated. Therefore, the N content is adjusted to 0.01% or less.
    [0043] [43] The balance of the aforementioned component contained in the base steel plate consists of Fe with the inevitable impurities. However, due to the following bases, it is preferable that at least one component selected from the group consisting of 0.01 to 1% Cr, 0.2% or less Ti, and 0.0005 to 0.08% B, and / or 0.003% to 0.03% of Sb are contained in the balance.
    [0044] [44] Cr: 0.01% to 1%
    [0045] [45] The component element Cr is effective for reinforcing steel and improving the hardening capacity of steel. To show such effects, it is preferable to adjust the Cr content to 0.01% or more. On the other hand, in the case where the Cr content exceeds 1%, the production cost for the base steel sheet is increased considerably. Therefore, it is preferable that the Cr content be adjusted to a maximum of 1%.
    [0046] [46] Ti: 0.2% or less
    [0047] [47] The Ti component is effective for reinforcing steel and improving steel toughness by refining crystalline grains. In addition, the Ti component element is also effective in forming nitrides in priority over the component element B mentioned below and having the effect of improving the hardening capacity of the dissolved-solid component element B. However, in the case where the Ti content exceeds 0.2%, the lamination load is greatly increased during hot rolling and the toughness of the hot-pressed component is decreased. Therefore, it is preferable that the Ti content is adjusted to a maximum of 0.2%.
    [0048] [48] B: 0.0005 to 0.08%
    [0049] [49] Component B is effective for improving the hardening capacity in hot pressing and the toughness after hot pressing. To show such effects, it is preferable to adjust the B content to 0.0005% or more. On the other hand, in the case where the B content exceeds 0.08%, the rolling load is extremely increased during hot rolling and fractures or the like are produced in the steel sheet due to the martensitic phases or the bainitic phases formed after hot rolling. Therefore, it is preferable that the B content is adjusted to a maximum of 0.08%.
    [0050] [50] Sb: 0.003 to 0.03%
    [0051] [51] The component element Sb is effective in suppressing the decarburized layer formed in the surface layer part of the steel sheet while cooling the steel sheet in the execution of a series of processes from the process of heating the steel sheet before from hot pressing to the hot pressing process. To show such an effect, it is necessary to adjust the Sb content to 0.003% or more. On the other hand, in the case where the Sb content exceeds 0.03%, the lamination load is greatly increased during hot rolling, thus decreasing productivity. Therefore, it is preferable that the Sb content is within the range of 0.003 to 0.03%.
    [0052] [52] Method for Production of the Hot Pressed Component
    [0053] [53] The steel plate mentioned above for hot pressing according to the present invention is hot pressed after being heated to a temperature ranging from the transformation point Ac3 to 100 ° C, thus forming the hot pressed component. The steel sheet is heated to a temperature equal to or greater than the transformation point Ac3 to form the hard phase such as a martensitic or similar phase by cooling in the hot pressing to increase the strength of the component. In addition, the heating temperature is at most 1000 ° C, because a large amount of ZnO is formed on the surface of the coating layer when the heating temperature exceeds 1000 ° C. Here, the heating temperature means the maximum arrival temperature of the steel plate. Although the average rate of temperature rise in heating prior to pressing, hot is not particularly limited to a certain rate, for example, an average rate of temperature rise ranging from 2 to 200 ° C / s is preferable. The amount of ZnO formed on the surface of the cladding layer and the amount of scale formed locally on the defective portions of the cladding layer are increased along with an increase in the high temperature residence time to which the steel sheet is exposed to a high temperature. Therefore, it is preferable to increase the average rate of temperature rise because scale formation is suppressed. In addition, although the retention time at the maximum arrival temperature of the steel sheet is also not particularly limited to a certain time, for the same reason as above, it is preferable to shorten the retention time. The retention time is preferably set to 300 seconds or less, more preferably to 120 seconds or less, and even more preferably to 10 seconds or less.
    [0054] [54] As a method of heating before hot pressing, a method of heating using an electric oven or a gas oven, a method of flame heating, a method of heating by conduction, a method of heating by high frequency induction, an induction heating method or the like can be illustrated. First Example
    [0055] [55] As a base steel plate, cold rolled steel plates were used, including component composition having 0.23% by weight of C, 0.25% by weight of Si, 1.2% by weight of Mn, 0 , 01% by weight of P, 0.01% by weight of S, 0.03% by weight of Al, 0.005% by weight of N, 0.2% by weight of Cr, 0.02% by weight of Ti , 0.0033% by weight of B, 0.008% by weight of Sb, and the balance of Fe and the inevitable impurities, and having the transformation point Ac3 of 820 ° C and the thickness of 1.6 mm. The electroplating treatment was applied to the surfaces of cold rolled steel sheets by changing the current density from 5 to 100 A / dm2 in a coating bath with a pH of 1.5 and a solution at a temperature of 50 ° C containing 200 g / l of nickel sulphate hexahydrate and 10 to 100 g / l of zinc sulphate hexahydrate. As shown in Tables 1 to 3, steel sheets 1 to 19 were prepared having coating layers that are different in Ni content (the balance is Zn and the inevitable impurities), coating weight and η phase content. In addition, for comparison with steel sheets Nos 1 to 19, steel sheets were prepared in 20 to 24 from a hot-dip galvanized steel sheet (GI), a galvannealed steel sheet (GA), a steel coated with Al - 5% Zn by hot dip (GL) which were made by applying hot dip coating to cold rolled steel sheets, and a cold rolled steel sheet without a coating layer. Tables 1 to 4 show the steel sheets 1 to 24 thus prepared.
    [0056] [56] Each of the steel plates No. 1 to 24 was heated in the electric oven or by direct energization under the heating condition specified in Tables 1 to 4 and, subsequently, cooled at a cooling rate of 50 ° C / s in a state in which each steel sheet was sandwiched between two dies made of aluminum. Next, the oxidation resistance described below was assessed. Tables 1 to 4 list the coating layer compositions, heating conditions, and results of the oxidation resistance assessment for each steel plate.
    [0057] [57] Resistance to oxidation: Each steel plate was heated under the heating condition illustrated in Tables 1 to 4 and, subsequently, the weight of each steel plate was measured and the change in weight was measured by comparing the weight after heating with weight before heating. Here the change in weight is obtained by adding the weight increased by the formation of scalings or ZnO and the weight reduced by dispersing the formed ZnO. The oxidation resistance is increased along with the reduction of the absolute value of the change in weight. Oxidation resistance was assessed based on the following criteria. When the evaluation result is "Excellent" or "Good", the objective of the present invention is satisfied.
    [0058] [58] Excellent: absolute value of change in weight <3 g / m2
    [0059] [59] Good: 3 g / m2 <absolute value of change in weight <6 g / m2
    [0060] [60] Poor: 5 g / m2 <absolute value of change in weight
    [0061] [61] As shown in Tables 1 to 4, it is evident that steel sheets 1 to 16 according to the present invention have small absolute values of change in weight and are excellent in resistance to oxidation.
    [0062] [62] The steel sheets mentioned above were not really worked by hot pressing. However, as mentioned above, as the oxidation resistance is influenced by the change in the coating layer due to heating prior to hot pressing, particularly by the behavior of the Zn contained in the coating layer, the oxidation resistance of the hot pressed component can be evaluated by the results of these examples. Second Example
    [0063] [63] Coating layers that were different in Ni content, coating weight, and η phase content, were formed on the surfaces of the base steel sheets in the same way as in the first Example. Thereafter, a compound (solid content ratio of 15% by weight) having at least one compound selected from the group consisting of a compound containing Si, a compound containing Ti, a compound containing Al, a compound containing Zr, and a compound containing Si and Zr which are described below, and the solvent balance has been applied to the coating layers. Subsequently, the steel sheets were baked under the condition that the maximum arrival temperature of the steel sheet was 140 ° C and, as shown in Tables 5 to 15, any one between a composite layer containing Si, a composite layer containing Ti, a composite layer containing Al, a composite layer containing Zr, and a composite layer containing Si and Zr, which were different in thickness, were thus formed by preparing the steel plates 1 to 32. Tables 5 to 15 show the plates steel from 1 to 32 so prepared.
    [0064] [64] Here, as a compound containing Si, a compound containing Ti, a compound containing Al, a compound containing Zr, the following compounds were used.
    [0065] [65] Silicone resin: KR-242A produced by Shin-Etsu Chemical Co., Ltd.
    [0066] [66] Lithium Silicate: 45 Lithium Silicate produced by Nissan Chemical Industries, Ltd.
    [0067] [67] Colloidal silica: SNOWTEX OS produced by Nissan Chemical Industries, Ltd.
    [0068] [68] Silane binding agent: KBE-403 produced by Shin-Etsu Chemical Co., Ltd.
    [0069] [69] Titanium bonding agent: ORGATIX TA-22 produced by Matsumoto Fine Chemical Co., Ltd.
    [0070] [70] Lithium Titanate: Lithium titanate produced by Titan Kogyo, Ltd.
    [0071] [71] Sodium aluminate: NA-170 produced by Asahi Chemical Co., Ltd.
    [0072] [72] Aluminum bonding agent: PLENACT AL-M produced by Ajinomoto Fine-Techno Co., Inc.
    [0073] [73] Zirconium acetate: zirconium acetate produced by SANEI KAKO Co., Ltd.
    [0074] [74] Zirconium bonding agent: ORGATIX ZA-65 produced by Matsumoto Fine Chemical Co., Ltd.
    [0075] [75] In addition, a solvent used when the silicone resin was used as a compound was the mixed thinner of monobutyl ethylene glycol ether and naphtha in a 55/45 mass ratio. In addition, a solvent used when a substance other than silicone resin was used as a compound was deionized water.
    [0076] [76] Steel sheets Nos 1 to 32 obtained in this way and illustrated in Tables 5 to 15 had the coating layers and composite layers formed on their surface in the order given above. Each steel plate was heated in the electric oven or by direct energization under the conditions specified in Tables 5 to 15 and, subsequently, cooled at a cooling rate of 50 ° C / s in a state in which each steel plate was sandwiched between dies made of aluminum. Thereafter the resistance to oxidation as in the case of the first Example and the adhesion of paint described below were evaluated. Tables 5 to 15 list the composition of the coating layer, the composition of the composite layer, the heating condition, and the results of the assessment of oxidation resistance and paint adhesion for each steel plate.
    [0077] [77] Paint adhesion: Samples of steel sheets were taken after heat treatment and chemical conversion treatment was applied to each sample under the standard condition using PB-SX35 produced by Nihon Parkerizing Co., Ltd. Subsequently , a coating film having a thickness of 20 pm was formed on the sample surface by electroplating coating under the 170 ° C cooking condition for 20 minutes using the GT-10HT Gray electroplating paint produced by Kansai Paint Co. , to prepare the specimen. Then, cuts were made that penetrated to the surface of the base steel plate on the surface with the prepared specimen to which the chemical conversion treatment and the electroplating coating were applied in a lattice pattern (10 by 10 squares, intervals 1 mm) using a cutting knife, and a peeling test with tape in the cross section to test the ink adhesion was evaluated based on the following criteria. When the evaluation result is "Excellent" or "Good", the sample is excellent in paint adhesion.
    [0078] [78] Excellent: without peeling
    [0079] [79] Good: peeled in 1 to 10 squares
    [0080] [80] Regular: peeled in 11 to 30 squares
    [0081] [81] Poor: peeled into 31 squares or more
    [0082] [82] As shown in Tables 5 to 15, in the examples of the present invention, it is evident that the steel sheet supplied with the composite layer is excellent in paint adhesion as well as in oxidation resistance.
    [0083] [89] In this example, each steel sheet was not actually worked by hot pressing. However, just as in the case of oxidation resistance, the addition of the hot-pressed component paint can be evaluated by the results of the examples. Industrial Applicability
    [0084] [90] The present invention is applicable to components such as suspension components or chassis structural components of an automobile produced by hot pressing.
    权利要求:
    Claims (4)
    [0001]
    Steel plate for hot pressing, characterized by the fact that it comprises: a base steel plate; and a coating layer that is formed on a base steel sheet surface at a coating weight of 10 to 90 g / m2 and contains 10 to 25% by weight of Ni and the balance of Zn and the inevitable impurities; where a phase content η contained in the coating layer is 5% by weight or less, and the base steel sheet has a composition of components that features: 0.15 to 0.5% by weight of C, 0.05 to 2.0% by weight of Si, 0.5 to 3% by mass of Mn, 0.1% by weight or less of P, 0.05% by weight or less of S, 0.1% by weight or less of Al, 0.01% by weight or less of N, 0.008 to 0.03% by weight of Sb, and the balance of Fe and the inevitable impurities.
    [0002]
    Steel sheet, according to claim 1, characterized by the fact that it also comprises at least one composite layer selected from the group consisting of: a composite layer containing Si, a composite layer containing Ti, a composite layer containing Al, and a composite layer containing Zr, wherein the composite layer is formed in the coating layer.
    [0003]
    Steel sheet according to claim 1 or 2, characterized by the fact that the base steel sheet still contains at least one component selected from the group consisting of 0.01 to 1 wt% Cr, 0.2% by weight or less of Ti, and 0.0005 to 0.08% by weight of B.
    [0004]
    Method for producing a hot-pressed component, characterized by the fact that it comprises: heating the steel sheet for hot pressing, as defined in any one of claims 1 to 3, to a temperature ranging from the transformation point Ac3 to 1000 ° C; and hot press the heated steel sheet.
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    同族专利:
    公开号 | 公开日
    US20130252017A1|2013-09-26|
    CA2817504C|2017-10-31|
    US10144196B2|2018-12-04|
    TW201229251A|2012-07-16|
    RU2548337C2|2015-04-20|
    MX2013005805A|2013-07-05|
    KR20130100340A|2013-09-10|
    MX353127B|2017-12-20|
    KR20150036816A|2015-04-07|
    EP2644751A4|2015-11-11|
    ZA201302948B|2015-09-30|
    EP2644751A1|2013-10-02|
    JP2012233249A|2012-11-29|
    AU2011332940A1|2013-06-13|
    CN103221581A|2013-07-24|
    CA2817504A1|2012-05-31|
    RU2013123693A|2014-11-27|
    CN103221581B|2016-06-08|
    BR112013012551A2|2016-08-09|
    AU2011332940B2|2015-10-08|
    JP5884151B2|2016-03-15|
    WO2012070482A1|2012-05-31|
    MY162755A|2017-07-14|
    TWI605136B|2017-11-11|
    KR101788114B1|2017-10-19|
    EP2644751B1|2018-08-22|
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    法律状态:
    2018-04-03| B06F| Objections, documents and/or translations needed after an examination request according art. 34 industrial property law|
    2019-06-04| B06T| Formal requirements before examination|
    2020-02-27| B07A| Technical examination (opinion): publication of technical examination (opinion)|
    2020-06-09| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law|
    2020-11-10| B09A| Decision: intention to grant|
    2021-01-12| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 18/11/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2010-261928|2010-11-25|
    JP2010261928|2010-11-25|
    JP2011000554|2011-01-05|
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    JP2011162680A|JP5884151B2|2010-11-25|2011-07-26|Steel sheet for hot press and method for producing hot press member using the same|
    JP2011-162680|2011-07-26|
    PCT/JP2011/076636|WO2012070482A1|2010-11-25|2011-11-18|Steel sheet for hot pressing and method for producing hot-pressed member using steel sheet for hot pressing|
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